Sounds to me like leaky fuel injectors. They are probably leaking fuel into the cylinders when you are shut off, then it's hard to start, but runs fine when all is burned off or blown out the tail pipe.
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'76 240D-Sold
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'88 300 TE, 165K-Sold
'64 Porsche 356C Cabriolet- under restoration
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'94 320E Wagon, 74K Miles-128K Miles JUNKED
'06 E350 Wagon, 84K Miles
07 SL550, 14K Miles
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