I agree use some form of treatment like Eastwoods or POR15 or KFZ to treat the rust.
For best results grind it to bare metal and leave no visible rust behind - those sand paper on angle grinder discs - stripping discs are ideal for this.
Don't be scared to remove trim.
Make sure you follow the instructions on the tin! And then make sure you use an appropriate primer before you apply top coats
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