Someone had the whole W123 shop manual (or most of it) on a torrent file. The link is somewhere on this forum.
Here's the CD, showing all the parts and how they fit together:
http://www.mercedesmanuals.com/Mercedes_Benz_W_123_Shop_Manual_p/w123.htm
Instructions are spare and intended for trained mechanics.
I don't get Haynes and Chilton. They spend a third of the book telling how to rebuild the engine, which no typical do-it-yourselfer will ever get close to -- but never stuff like how to effectively pry off the window trim or troubleshoot the vacuum system.
DieselGiant (
www.dieselgiant.com) has great free instructions for a lot of common jobs. And even more instructional DVDs for sale.
Also, check out the forum's wiki:
http://www.peachparts.com/Wikka/DoItYourSelf