I recall getting same message almost every time I started the car no matter how long it sat. My main battery checked out OK at several places I took it to incl. a Mercedes Dealer that used a Mercedes tester.
The battery was fairly old (8 years) so I got a new one. Message went away and I have not had any other issues in 2 years.
I think batteries may loose their ability to hold a charge over time.
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-- Chris
'95 E300, 216k miles, Silver Surfer
'05 E320 CDI, 138k miles
'07 S550 4matic, 69k miles
Gone but not forgotten:
'76 300D, 350k miles?, SOLD in 1995 
'75 240D, 300k miles, SOLD in 1991
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