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Don't know the exact answer to your question in that your ML may not be made to tolerate Ethanol/alcohol.
But, Ethanol doesn't have near as much energy per gallon as premium gasoline, so you can expect your miles per gallon to go way down.
It may look cheaper per gallon, but cost per mile is much higher.
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KenP
1996 S500 W140 Coupe
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