ESP is a more advanced ASR. Its more of a stability control in all driving conditions while ASR is more of a traction control to get you moving.

http://www2.mercedes-benz.co.uk/content/unitedkingdom/mpc/mpc_unitedkingdom_website/en/home_mpc/vans/home/products/new_vans/vito_new/overview/safe/driving_stability.0002.html