Just an FYI, I had the same problem with my 94 E320 after changing the head gasket. I know it is possible to inadvertantly switch the vaccum lines which I was careful not to do. The thing I did do though was to accidentally break the vacuum "T" (doesn't actually look like a "T", has 3 vacuum connections) that hooks to the top of the "switch over valve". I bought a new one at the dealer thinking I was done.
After driving the car the CEL came on, I checked the code and got the code #4. After reading this article I checked the vacuum lines to the SOV and for some reason no vacuum at the "T" fitting outlets. All the lines to the T were fine, but for some odd reason no vacuum at the outlets. It turns out I had a defective vacuum "T", there is a piece of hard vacuum line between the 2 outlets on the "T" that was obstructed somehow, I managed to run a small drill bit in the "T" and open the passage way, being careful not to puncture the rubber of the "T". Finally I had vacuum present at both outlets that connect to the SOV and no more CEL problems. I just thought I would pass this along for things to check when the code 4 is present.
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 1999 SL500 87K
1994 E320 112K
1998 Ford Ranger - the daily driver 274K and no major repairs (an indestructible truck)
1978 Pontiac Trans Am 110K
1977 Pontiac Trans Am 130K
1999 SL500 87K (the garage queen, only out in the summer)
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