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Black smoke is unburned fuel, but is also carbon build-up burning off. Carbon builds up inside these engines, and it is healthy for them if once in a while you do a wide open throttle acceleration while getting on the highway to get the RPM up high which burns out all that carbon.
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Andrew '04 Jetta TDI Wagon
'82 300TD ~ Winnie ~ Sold '77 300D ~ Sold
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