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You can charge without running the compressor, but why? Just charge with the compressor running - it will seem to "suck" the refrigerant in much more quickly. You can start out charging both high and low sides with the system off, but make absolutely sure that you shut off your high side valve BEFORE starting the car, or you'll be eating some shrapnel!
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08 W251 R350
97 W210 E320
91 W124 300E
86 W126 560SEL
85 W126 380SE Silver
85 W126 380SE Cranberry
79 W123 250
78 W123 280E
75 W114 280
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