I am guessing that you have a problem with the air injection. There is a valve that will allow one way travel of the injected air only. This could be the cause. I doubt the cats.
------------------
Benzmac:
Donnie Drummonds
1992 500E (very soon I hope

1981 280GE SWB
ASE CERTIFIED MASTER AUTO TECHNICIAN
SERVICE MANAGER FOR 14 BAY FACILITY
MERCEDES SPECIALIST 8 YRS
PARTNER IN MERCEDESSHOP.COM