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The shock absorber on the serpentine belt tensioner could have worn bushings. This will make a real racket, especially with a cold engine. I recently replaced them on my '93 300SD and '95 S350. We discovered the source of the noise by placing a finger on the upper shock mount and pressing down. The noise went away! The bushings are not availble seperately. You have to replace the shock. Give it a try.
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