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Had you tried to "jump-start" the car after you replaced the battery?
Obviously, there is a problem with the replacement...check the voltage at the terminals with everything off (incl. the engine). That should tell you a little about the condition of the battery. 14.5V sounds like your charging system is operating as it should.
Perhaps the climate control mishaps are coincidental, but I would fix the battery problem first to see if the problems correct themselves...
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2009 ML350 (106K) - Family vehicle
2001 CLK430 Cabriolet (80K) - Wife's car
2005 BMW 645CI (138K) - My daily driver
2016 Mustang (32K) - Daughter's car
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