If I read it right, you're temps went up ~ 15ºC when you switched from plain water to an ~ 50/50 water/MB coolant mix and nothing else?
Plain water is better at heat transfer, but, that's a big difference.
I'd suspect the coolant system isn't "burped". Run the heater, disconnect the top rad hose and whatever else you may find in "search" using
or as a keyword. FWIW