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One word comes to mind "SAFETY".
Lead-acid batteries produce flammable hydrogen gas while being charged. This highly explosive gas, generated within the cells, will expand and seep out of the vent caps. A cigarette, tool, or spark from any source could ignite the gas, causing the battery to explode.
1) Connect the first cable to the positive (+) terminal of the good battery; then attach the other end of that cable to the positive (+) terminal of the dead battery.
2) Next, attach the second cable to the negative (-) terminal of the good battery, and make the fourth and last connection to a clean metal part, such as the engine block of the car being energized, rather than to its negative battery terminal. This completes the electrical circuit, as if it were connected to the dead battery, but if sparks are produced, it serves to keep them away from any explosive battery gases.
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