i have a e320 2002 benz both rear windows dont go up n down when car is running . but if i put the car keys on the on position the work

Sounds like a problem with the LCP (lower control panel) which is the fancy name for the window switch module. Either the module itself is faulty or something in the car is corrupting communication over the body CAN network. Need to connect an SDS and see what is and isn't talking on the network, and from there figure out why.

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90 300TE 4-M
Turbo 103, T3/T04E 50 trim
T04B cover .60 AR
Stage 3 turbine .63 AR
A2W I/C, 40 LB/HR
MS2E, 60-2 Direct Coil Control
3" Exh, AEM W/B O2
Underdrive Alt. and P/S Pulleys,
Vented Rear Discs, .034 Booster.
3.07 diffs 1st Gear Start

90 300CE 104.980
Milled & ported head, 10.3:1 compression
197° intake cam w/20° advancer
Tuned CIS ECU
4° ignition advance
PCS TCM2000, built 722.6
600W networked suction fan
Sportline sway bars
V8 rear subframe, Quaife ATB 3.06 diff