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-   -   Goodbye R134a, hello HFO-1234yf (http://www.peachparts.com/shopforum/diesel-discussion/303738-goodbye-r134a-hello-hfo-1234yf.html)

Doktor Bert 06-28-2013 11:04 AM

Quote:

Originally Posted by DeliveryValve (Post 3167358)
And Mexican refrigerant is about the same hit and miss quality as Chinese refrigerant...

Dad's cylinder is marked Technical Chemical Company Dallas, Texas. DuPont was making refrigerant in a Mexican plant as well as some others, as we have some DuPont R134 marked Made in Mexico.

I have seen 'no label' cylinders too, which I avoid....FWIW

vstech 06-28-2013 12:38 PM

Quote:

Originally Posted by Doktor Bert (Post 3167352)
And you can buy any refrigerant in Mexico apparently. My Dad bought an unopened cylinder of R22 from a neighbor for $100.00.....

I think you can buy any refrigerant from any neighbor anywhere. not legally of course, but it's doubtfull the epa is following up on residents selling stuff...

does your dad live in mexico? or did the neighbor get it from there?

Doktor Bert 06-28-2013 12:53 PM

Quote:

Originally Posted by vstech (Post 3167428)
I think you can buy any refrigerant from any neighbor anywhere. not legally of course, but it's doubtfull the epa is following up on residents selling stuff...

does your dad live in mexico? or did the neighbor get it from there?

The neighbor brought back a varied assortment of refrigerants, 502, 410, R22, R12, R134, etc.

Doktor Bert 06-28-2013 04:21 PM

I do a lot of A/C work on the side. The shop where I used to work has a 2000 F150 and they asked me to come out and do the A/C on it. With a new condensor and a few modifications, vent temps at 100°F ambient are 35°F at idle and 30°F at 70 mph.

The thing I like about Ford is the larger condensor/evaporator (compared to GM) and the orifice tube system which is completely tuneable....

Doktor Bert 06-28-2013 04:23 PM

1 Attachment(s)
In contrast, my W116 with an expansion valve/ETR system (on R12) will only pull down to 33°F-35°F at 70 mph and about 40° at idle...

tjts1 07-05-2013 07:03 PM

Daimler says France blocking some new registrations
 
Quote:

French authorities have refused to register Mercedes A-Class, B-Class and SL cars assembled since June 12, even though German authorities have approved them, a Daimler spokesman said.

Usually the approval in France follows on automatically from the German approval.

"We have no explanation for why the registration in France was not yet accepted," the spokesman said.

An EU official familiar with the matter said that France had blocked the registration because the cars contained a coolant that was not permitted in the European Union.

The person added that the French transport ministry had informed the Commission about their plans this week and that the Commission would discuss the matter at their next automotive meeting in mid July.

French government officials did not immediately return calls seeking comment.

Daimler said in September that 1234yf, the only air conditioning coolant on the market that conforms to a new European Union directive on greenhouse gases, could be the primary source for a vehicle fire.

It and rival Volkswagen (VOWG_p.DE) are both developing expensive carbon dioxide-based air conditioning systems in order to avoid what they say is a fire hazard posed by Honeywell (HON.N) and DuPont's (DD.N) new refrigerant HFO-1234yf, which emits poisonous hydrogen fluoride gas when it burns.
Daimler says France blocking some new registrations | Reuters

Codifex Maximus 07-06-2013 12:53 AM

I saw a video where a guy was trying to keep a canister of 1234 lit. He had to keep the ignition source in the stream of refrigerant just to keep it lit.

Stuff doesn't seem to burn very well.

vstech 07-06-2013 01:43 AM

Quote:

Originally Posted by tjts1 (Post 3170967)

... so instead of a chemical that can burn, they are installing one that's very high pressure (over 2500psi at condenser head pressures...) and a leak can suffocate you in an enclosed space... like a small car.
I mean, CO2 in liquid form is stable, but heated, up to 120 which is COMMON for R12 and 134... and the pressure goes off the chart...
the heat transfer is going to SUCK... they'll have to make the condensers out of cast iron or Stainless steel to handle the pressures, and I guess copper plate them to get heat out of them...
http://i33.photobucket.com/albums/d9...kers/co2pv.gif


note, this is a chart for pressures possible in an overfilled bottle... I couldn't find a working PT chart to compare with R12...

vstech 07-06-2013 01:56 AM

ok,
THIS article appears to state that R744 refrigeration does not use standard Phase Change cooling like all other refrigerants, due to the tremendous pressure possibilities... they use a gas cooling system instead of a typical condensing refrigeration system...
the math is waaaaaay above my head though, so perhaps I am misunderstanding the article...

Codifex Maximus 07-06-2013 07:11 AM

Quote:

Originally Posted by vstech (Post 3171099)
... so instead of a chemical that can burn, they are installing one that's very high pressure (over 2500psi at condenser head pressures...) and a leak can suffocate you in an enclosed space... like a small car.
I mean, CO2 in liquid form is stable, but heated, up to 120 which is COMMON for R12 and 134... and the pressure goes off the chart...
the heat transfer is going to SUCK... they'll have to make the condensers out of cast iron or Stainless steel to handle the pressures, and I guess copper plate them to get heat out of them...

I'll bet the torque needed to turn such a compressor would make a C02 based system unfeasible. EPIC FAIL

JHZR2 07-06-2013 10:33 AM

Quote:

Originally Posted by Codifex Maximus (Post 3171119)
I'll bet the torque needed to turn such a compressor would make a C02 based system unfeasible. EPIC FAIL

Says who? Have you run EOSs to determine shaft work requirements to get the applicable PV change?

Im not a fan of this new stuff, but speculation without basis doesnt help anyone.

Codifex Maximus 07-07-2013 04:09 AM

Quote:

Originally Posted by JHZR2 (Post 3171162)
Says who? Have you run EOSs to determine shaft work requirements to get the applicable PV change?

Im not a fan of this new stuff, but speculation without basis doesnt help anyone.

Well, I guess I made some assumptions.

I assumed that higher pressure would require additional power but it appears that overall efficiency of C02 more than makes up for any differences in power requirements with R134a.

I found a study that concluded that CO2 actually performed 20% better than R134a with a properly built and tuned system that utilized a two stage compressor.

The benefits of CO2 are even better realized in a heat pump system that can even heat your water in a home installation.

Very interesting.

Doktor Bert 07-08-2013 02:35 PM

Let's just be honest, shall we????

R12 became 'dangerous' only after DuPont's patent lapsed. Think R134a is safe??? Look at its chemical composition....FWIW

tjts1 08-02-2013 02:38 PM

France Declares War On Germany By Halting Mercedes Sales
 
Quote:

In the most stunning development in Franco-German relations since Hitler's forces crossed the Maginot Line, the French government has moved to halt sales of some new Mercedes-Benz models in their country. Zut alors! P

No, it's not delayed retalliation for German dickery during the Second World War. (Probably not, anyway.) It's because of refrigerant. France is following a new EU regulation that bans the use of a refrigerant called R134a, a global-warming gas which Car and Driver says is 1,400 times more potent than carbon dioxide. P

Mercedes asked for an extension to 2017 to implement the changeover to the new refrigerant. The German government granted this extension, but the French refuse to recognize it.P

Reuters reports that in response the automaker took France to court, and administrative judges ordered the government to lift the ban, but now they refuse to do so.P
France Declares War On Germany By Halting Mercedes Sales
http://img.gawkerassets.com/img/18vs.../ku-bigpic.jpg

eatont9999 08-02-2013 03:25 PM

Quote:

Originally Posted by Doktor Bert (Post 3172150)
Let's just be honest, shall we????

R12 became 'dangerous' only after DuPont's patent lapsed. Think R134a is safe??? Look at its chemical composition....FWIW


Exactly. Funny how those two correlate in such a close amount of time. I remember seeing the propaganda ads on TV about how dangerous CFCs and Freon are. I think it was the early 90's. Even the teachers in school gave lectures and held classes on the subject.


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